Could
Nanotechnology lead to cleaner water?
Not all
nanopores are created equal. For starters, their diameters vary between 1 and
10 nm. The smallest of these
nanopores, called Single Digit Nanopores (SDNs), having the diameters of less
than 10 nm and only recently have been used in experiments for precision
transport measurements. If these gaps can be filled there is a chance to discover
new mechanisms of molecular and ionic transport at the nanoscale that may apply
to a host of new technologies. SDNs can be tailored to sieve ions efficiently
from seawater and serve as membranes for seawater desalination; differentiate
between polar and nonpolar fluids; enhance proton transport in fuel cell
applications; and generate electricity from osmotic power harvesting.
The team of
Lawrence Livermore National Laboratory (LLNL) scientists and colleagues from
seven other institutions, led by the Massachusetts Institute of Technology
(MIT), have reviewed recent SDN experiments and identified critical gaps in
understanding nanoscale hydrodynamics, molecular sieving, fluidic structure and
thermodynamics and also analyzed seven knowledge gaps in the understanding of
nanoscale behaviour. For example, scientists have seen a counterintuitive
slip-flow enhancement in nanopores, in which the narrowest nanopores
demonstrate the highest mass transport rates. Other notable knowledge gaps
include fluid phase boundaries in SDNs that are distorted relative to their
bulk fluid counterparts, and nonlinear, correlative effects on ion transport
through SDNs that are not observed in larger diameter nanopores.
A better
understanding of transport at the nanoscale can lead to innovative technologies
such as new membranes for water purification, new gas-permeable materials and
energy storage devices.
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Source: Nano Magazine
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